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Barrier Films for Flexible Electronics 2013-2023, Needs Players & Opportunities

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Published Date : 2013-04-01

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No. of Pages : 105

Product Synopsis

Although it is possible to print many different kinds of electronic displays, in order for them to be commercially successful, they must be robust enough to survive for the necessary time and conditions required of the display. This condition has been a limitation of many printable electronic displays. Beyond printability and functionality, one of the most important requirements is encapsulation. Many of the materials used in printed electronic displays are chemically sensitive, and will react with many environmental components. This highly targeted report from IDTechEx technology analyst Dr Harry Zervos gives an in-depth review of the issues, as well as forecasts for OLEDs and OPV, in order to understand the influence that the development of flexible barriers will have on the... Read More

Table Of Content

Table of Contents



3.1. Important considerations of surface smoothness
3.2. Micro Defects
3.2.1. Crystalline regions
3.2.2. Pinholes
3.2.3. Smoothness / Cracks-Scratches
3.2.4. Nanodefects

4.1. 3M
4.2. Amcor Flexibles Singen GmbH
4.3. CPI
4.4. Fraunhofer - POLO Alliance
4.5. GE
4.6. Tera Barrier
4.7. Vitex
4.8. Other technologies - High barrier adhesives
4.9. Best performing barriers developed to date

5.1. The Calcium test
5.2. MOCON
5.3. Illinois Instruments
5.4. Fluorescent Tracers
5.5. Black Spot Analysis
5.6. Tritium Test
5.7. CEA
5.8. 3M
5.9. IMRE
5.10. Mass Spectrocopy - gas permeation (WVTR & OTR potential applications)

6.1. The potential significance of organic and printed inorganic electronics
6.2. Forecasts for flexible electronics 2012-2022
6.3. Barrier films market size





List of Tables

2.1. Water vapor and oxygen transmission rates of various materials
2.2. Requirements of barrier materials
3.1. Oxygen transmission rates of polypropylene with various coatings.4, 7
4.1. Overview of promising high barrier technologies
5.1. Lower detection limits of several barrier performance measurement techniques
6.1. Leading market drivers 2022
6.2. Total market value of flexible vs. rigid electronics 2012-2022
6.3. Barrier layer area forecasts 2012-2022 in square meters
6.4. Barrier layer market forecasts 2012-2022 in US$

List of Figures

1.1. Examples of flexible OLED displays by SONY and AddVision
1.2. Flexible OLED fabricated using IMRE's high barrier substrate and encapsulation technique44
1.3. Flexible Solar Cell developed by Fraunhofer ISE
2.1. Schematic diagrams for encapsulated structures a) conventional b) laminated c) deposited in situ4
2.2. Scanning electron micrograph image of a barrier film cross section6
3.1. Visual defects of a selection of materials with barrier films highlighted through calcium corrosion test. Optical microscope magnification 10x.44
3.2. SEM pictures of the Atmospheric Plasma Glow Discharge deposited silica-like films on polymer substrates. Left: Film with embedded dust particles . Right: uniform film27
3.3. OTR as a function of defect density, the correlation between defect density and the oxygen transmission rate
3.4. SEM image of a pinhole defect formed from a dust particle32
3.5. Scanning electron microscope image of ITO coated on parylene/polymer film34
3.6. The measurement of OLED's lifetime of SiON/PC/ITO and SiON/parylene/PC/parylene/ITO substrate34
4.1. Calcium test results demonstrating superior WVTR performance
4.2. 3M barrier film development roadmap
4.3. Amcor (formerly Alcan) Packaging flexible barrier based on PET and SiOx47
4.4. DuPont Displays technology pipeline
4.5. Scanning electron micrograph of a thin hybrid polymer coating on SiOx deposited on a flexible PET film 46
4.6. OTR values achieved with different POLO multilayers46
4.7. Schematic of cross section of graded barrier coating and complete barrier film structure1.
4.8. Transparency of GE's UHB film versus wavelength
4.9. Examples of polymer multi-layer (PML) surface planarization a) OLED cathode separator structure b) high aspect ratio test structure.3, 8
4.10. Vitex multilayer deposition process8.
4.11. SEM cross section of Vitex Barix material with four dyads.
4.12. Optical transmission of Vitex Barix coating8.
4.13. Edge seal barrier formation by deposition through shadow masks10
4.14. Three dimensional barrier structure. Polymer is shown in red, and oxide (barrier) shown in blue10
4.15. Schematic of flexible OLED with hybrid encapsulation31
4.16. Corning flexible glass showcased at SID 2011
4.17. Matchless: AGC's ultra-thin sheet glass may be thin, but it can take the heat
4.18. AGC's ultra-thin sheet glass rolled into a coil
4.19. Area sealing55
4.20. DELO's light curing adhesive solution for electrophoretic displays55
4.21. Performance characteristics of DELO's light-curing materials55
4.22. Specifications on WVTR for different applications, as seen by Vitex Systems36
4.23. 3M specifications on WVTR and OTR for high barrier applications with stringent requirements 14
5.1. 2.25 mm2 area of a 50 nm layer of Ca deposited onto barrier coated PET viewed through the substrate. i. Image after 1632 h of exposure to atmosphere; ii. Image analysis whereby the grey scale of Ca degradation is processed to yiel
5.2. A simple set-up for measuring optical transmission of calcium test cells48
5.3. MOCON's Aquatran"! Model 138
5.4. MOCON's Aquatran"! schematic38
5.5. MOCON's OX-TRANR Model 2/1039
5.6. Silica induced black spots, letters A & B mark black spots with a centralized black dot (silica particle)32
5.7. Black spot formation and growth mechanisms 32
5.8. General Atomics HTO WVTR testing apparatus40
6.1. Leading market drivers 2022
6.2. Total market value of flexible vs. rigid electronics 2012-2022
6.3. Barrier layer area forecasts 2012-2022 in square meters
6.4. Barrier layer market forecasts 2012-2022 in US$
6.5. Size of opportunity
7.1. The iRex iLiad and the Amazon Kindle rigid e-book readers
7.2. E Ink flexible electrophoretic display and color electrophoretic display by SAMSUNG LCD, demonstrated at SID 2008
7.3. Lithium test sample with thin film encapsulation after 24 hrs in the damp heat test at 85°C/85% relative humidity. B. Similar lithium test sample after 200 hrs in the same damp heat test with optimized barrier structure.

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